Artigo Revisado por pares

An efficient protocol for the synthesis of fenestrane derivatives

1991; Elsevier BV; Volume: 32; Issue: 19 Linguagem: Inglês

10.1016/s0040-4039(00)71248-2

ISSN

1873-3581

Autores

William A. Smit, S.M. Buhanjuk, S. O. Simonyan, А. С. Шашков, Yu. T. Struchkov, A.I. Yanovsky, R. Caple, A. S. Gybin, Lawrence G. Anderson, Jeffery A. Whiteford,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

A short route for the synthesis of several fenestrane derivatives is suggested based on the sequence: (A) etherification of μ-cobaltcarbonyl complexes of 1,6-enyn-5-ols with unsaturated alcohols, (B) intramolecular Khand-Pauson reaction and, (C) [2+2] photocycloaddition.

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