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Selective oxidations of allylic alcohols using vanadyl and cobalt(II) alkyl phosphonate modified silicas

2004; Elsevier BV; Volume: 45; Issue: 23 Linguagem: Inglês

10.1016/j.tetlet.2004.04.067

1873-3581

Magdalena Jurado‐Gonzalez, Alice C. Sullivan, John R. Wilson,

Catalysis and Oxidation Reactions

A range of allylic alcohols can be selectively oxidised to either the corresponding epoxide or the enone in good yields using catalytic quantities of vanadyl or cobalt(II) alkyl phosphonate modified silicas, CoEPS3 and VOEPS3 and tert-butyl hydroperoxide.