A Novel Diastereoselective Synthesis of ( Z )-Fluoroalkenes via a Nozaki−Hiyama−Kishi-Type Reaction
2005; American Chemical Society; Volume: 70; Issue: 5 Linguagem: Inglês
10.1021/jo048093g
ISSN1520-6904
AutoresGuillaume Dutheuil, Xinsheng Lei, Xavier Pannecoucke, Jean‐Charles Quirion,
Tópico(s)Synthesis and Reactions of Organic Compounds
ResumoA highly diastereoselective and straightforward synthesis for (Z)-2-fluoroallylic alcohols via a Nozaki-Hiyama-Kishi-type reaction with the corresponding bromofluoroolefins was developed, providing an easy access to highly interesting fluorinated synthons.
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