Mn(OAc)3—an efficient oxidant for regeneration of DDQ: deprotection of p-methoxy benzyl ethers
2000; Elsevier BV; Volume: 41; Issue: 52 Linguagem: Inglês
10.1016/s0040-4039(00)01855-4
ISSN1873-3581
AutoresGangavaram V. M. Sharma, B. Lavanya, M. Arulprakasajothi, Palakodety Radha Krishna,
Tópico(s)Chemical Synthesis and Reactions
ResumoMn(OAc)3 has been successfully developed as a new oxidant for the regeneration of DDQ from HDDQ. This DDQ regeneration technique, making use of 3 equiv. of Mn(OAc)3–DDQ (10 mol%), was applied to the deprotection of p-methoxy benzyl (PMB) ethers.
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