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Rb 2 [Ga 4 (HPO 4 )(PO 4 ) 4 ]·0.5H 2 O: A New Gallium Phosphate Containing Four-, Five, and Six-Coordinated Gallium Atoms

1996; American Chemical Society; Volume: 35; Issue: 25 Linguagem: Inglês

10.1021/ic960488y

1520-510X

Kwang‐Hwa Lii,

Zeolite Catalysis and Synthesis

The synthesis and structure of a new gallium phosphate is described; the framework structure consists of four-, five-, and six-coordinated Ga atoms linked by phosphate groups to form eight -membered rings that house the rubidium cations and water molecules, and which are connected to give rise to infinite channels with eight-membered windows along [100].