ChemInform Abstract: Bi 65 Cu 13 Ge 41 O 6 Br 122 , a Low‐Valent Compound of High Structural Complexity Featuring the Trigonal Anion [O(Ge II Br 2 ) 3 ] 2‐ with an sp 2 ‐Hybridized μ 3 ‐Oxide Ion.

Artigo

ChemInform Abstract: Bi 65 Cu 13 Ge 41 O 6 Br 122 , a Low‐Valent Compound of High Structural Complexity Featuring the Trigonal Anion [O(Ge II Br 2 ) 3 ] 2‐ with an sp 2 ‐Hybridized μ 3 ‐Oxide Ion.

2014; Wiley; Volume: 45; Issue: 8 Linguagem: Inglês

10.1002/chin.201408002

ISSN

1431-5890

Autores

Alexander Gerisch, Anna Isaeva, Michael Ruck,

Tópico(s)

Inorganic Chemistry and Materials

Resumo

Abstract (Bi 5 ) 2 (Bi 9 ) 6 [O(GeBr 2 ) 3 ] 6 [Cu 6 Ge 5 Br 20 ] [BiCu 7 Ge 18 Br 66 ] is obtained by very slow cooling of a melt of Bi, BiBr 3 , Cu, and partly oxidized Ge (1000 °C, 1 d, 1 K/h cooling rate).

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ChemInform Abstract: Bi 65 Cu 13 Ge 41 O 6 Br 122 , a Low‐Valent Compound of High Structural Complexity Featuring the Trigonal Anion [O(Ge II Br 2 ) 3 ] 2‐ with an sp 2 ‐Hybridized μ 3 ‐Oxide Ion.