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Stereoselective synthesis of substituted N-heterocycles via sequential cross metathesis—reductive cyclization

2004; Elsevier BV; Volume: 46; Issue: 1 Linguagem: Inglês

10.1016/j.tetlet.2004.11.030

1873-3581

Julian Gebauer, Purnama Dewi, Siegfried Blechert,

Advanced Synthetic Organic Chemistry

A diastereoselective synthesis of substituted mono- and bicyclic-piperidine and pyrrolidine derivatives is presented, employing a highly selective cross metathesis (CM) reaction followed by a domino reduction–cyclization process.