ChemInform Abstract: Silicon‐Oxygen Bond‐Forming Reactions Upon Addition of Silanes and Silyl Halides to the 16‐Electron Alkoxyiridium Complexes trans‐ROIr(CO)(P(p‐tol)3)2 (R: Me or Ph; p‐tol: p‐Tolyl). Crystal and Molecular Structure of H2Ir(CO)(SiMe2Ph)(P(p‐tol)3)2.
1989; Wiley; Volume: 20; Issue: 1 Linguagem: Inglês
10.1002/chin.198901239
ISSN1431-5890
AutoresB. J. RAPPOLI, Thomas S. Janik, M. R. CHURCHILL, Jeffrey S. Thompson, Jim D. Atwood,
Tópico(s)Synthesis and characterization of novel inorganic/organometallic compounds
ResumoAbstract The silanes (II) add oxidatively to the alkoxo‐Ir complexes (I); the resulting complexes undergo reductive elimination of the alkoxysilanes (IV) with ultimate formation of the dihydridosilyl‐Ir(III) complexes (III).
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