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A Simple Procedure for Selective Acylation of the Less Reactive Hydroxyl Functionality in Some Dihydroxylated Compounds

1995; Taylor & Francis; Volume: 25; Issue: 24 Linguagem: Inglês

10.1080/00397919508011488

1532-2432

Emil Pop, Ferenc Sóti, Marcus E. Brewster,

Synthesis and Biological Evaluation

Abstract Phenolic (3′) esters (acetate, N-t-Boc glycinate) of the (+) 3S, 4S 5′(1′,1′-dimethylheptyl)-7-hydroxy-δ6−tetrahydrocannabinol (dexanabinol) were synthesized via the 7′-trifluoroacetate followed by acylation and subsequent deprotection.