Oxygen-Promoted Palladium(II) Catalysis: Facile C(sp 2 )−C(sp 2 ) Bond Formation via Cross-Coupling of Alkenylboronic Compounds and Olefins
2004; American Chemical Society; Volume: 6; Issue: 22 Linguagem: Inglês
10.1021/ol0483192
ISSN1523-7060
AutoresCheol Hwan Yoon, Kyung Soo Yoo, Sung Wook Yi, Rajesh Mishra, Kyung Woon Jung,
Tópico(s)Oxidative Organic Chemistry Reactions
ResumoOxygen-promoted Pd(II) catalysis facilitated the synthesis of conjugated dienes by cross-coupling of alkenylboronic compounds and various olefins including highly substituted alkenes and cyclohexenone. Under mild conditions, these versatile reactions were efficient and highly stereoselective.
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