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Palladium(0) Complexes of a 15-Membered Macrocyclic Triolefin as a Recoverable Catalyst - Monomer- and Polystyrene-Anchored Versions

2000; Wiley; Volume: 2000; Issue: 2 Linguagem: Inglês

10.1002/(sici)1099-0690(200001)2000

1434-193X

Jordi Cortès, Marcial Moreno‐Mañas, Roser Pleixats,

Carbon dioxide utilization in catalysis

European Journal of Organic ChemistryVolume 2000, Issue 2 p. 239-243 Full Paper Palladium(0) Complexes of a 15-Membered Macrocyclic Triolefin as a Recoverable Catalyst - Monomer- and Polystyrene-Anchored Versions Jordi Cortés, Jordi Cortés Department of Chemistry. Universitat Autònoma de Barcelona, Cerdanyola. 08193-Barcelona. Spain Fax: (internat.) + 34-93/581-1265Search for more papers by this authorMarcial Moreno-Mañas, Marcial Moreno-Mañas iqorb@cc.uab.es Search for more papers by this authorRoser Pleixats, Roser Pleixats Department of Chemistry. Universitat Autònoma de Barcelona, Cerdanyola. 08193-Barcelona. Spain Fax: (internat.) + 34-93/581-1265Search for more papers by this author Jordi Cortés, Jordi Cortés Department of Chemistry. Universitat Autònoma de Barcelona, Cerdanyola. 08193-Barcelona. Spain Fax: (internat.) + 34-93/581-1265Search for more papers by this authorMarcial Moreno-Mañas, Marcial Moreno-Mañas iqorb@cc.uab.es Search for more papers by this authorRoser Pleixats, Roser Pleixats Department of Chemistry. Universitat Autònoma de Barcelona, Cerdanyola. 08193-Barcelona. Spain Fax: (internat.) + 34-93/581-1265Search for more papers by this author First published: 17 December 1999 https://doi.org/10.1002/(SICI)1099-0690(200001)2000:2 3.0.CO;2-RCitations: 52AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Preparation of the 15-membered cycle (E,E,E)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6,11-triazacyclopentadeca3,8,13-triene (8) is reported. This cyclic triolefin forms a stable Pd0 complex 9 which catalyzes several cross-coupling reactions and can be recovered. Anchoring to a polystyrene framework affords a solid version of the catalyst, which is recovered by simple filtration and reused without loss of catalytic activity. Citing Literature Volume2000, Issue2January 2000Pages 239-243 RelatedInformation