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Giant gate-tunable bandgap renormalization and excitonic effects in a 2D semiconductor

2019; American Association for the Advancement of Science; Volume: 5; Issue: 7 Linguagem: Inglês

10.1126/sciadv.aaw2347

2375-2548

Zhizhan Qiu, Maxim Trushin, Hanyan Fang, Ivan Verzhbitskiy, Shiyuan Gao, Evan Laksono, Ming Yang, Pin Lyu, Jing Li, Jie Su, Mykola Telychko, Kenji Watanabe, Takashi Taniguchi, Jishan Wu, A. H. Castro Neto, Li Yang, Goki Eda, Shaffique Adam, Jiong Lu,

Quantum and electron transport phenomena

Understanding the remarkable excitonic effects and controlling the exciton binding energies in two-dimensional (2D) semiconductors are crucial in unlocking their full potential for use in future photonic and optoelectronic devices. Here, we demonstrate large excitonic effects and gate-tunable exciton binding energies in single-layer rhenium diselenide (ReSe2) on a back-gated graphene device. We used scanning tunneling spectroscopy and differential reflectance spectroscopy to measure the quasiparticle electronic and optical bandgap of single-layer ReSe2, respectively, yielding a large exciton binding energy of 520 meV. Further, we achieved continuous tuning of the electronic bandgap and exciton binding energy of monolayer ReSe2 by hundreds of milli-electron volts through electrostatic gating, attributed to tunable Coulomb interactions arising from the gate-controlled free carriers in graphene. Our findings open a new avenue for controlling the bandgap renormalization and exciton binding energies in 2D semiconductors for a wide range of technological applications.