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Structural characterization of ZnSO4-K2SO4-NaCl glasses

2019; Elsevier BV; Volume: 524; Linguagem: Inglês

10.1016/j.jnoncrysol.2019.119639

1873-4812

Emily T. Nienhuis, Muad Saleh, José Marcial, Kyle W. Kriegsman, Jason M. Lonergan, Andrew Lipton, Xiaofeng Guo, John S. McCloy,

Crystal Structures and Properties

Glasses with compositions xNaCl-(50-x/2)K2SO4-(50-x/2)ZnSO4, x = 0 to 30 (in mol%), were characterized via vibrational spectroscopy and X-ray pair distribution function (xPDF) analysis. The xPDF's were modeled using Empirical Potential Structure Refinement (EPSR). From the modeled xPDF, the deconvoluted xPDFs were obtained along with cation-anion coordination numbers. The sulfate environment was elucidated through analysis of the vibrational spectroscopy paired with xPDFs. As determined via these techniques, the SO42− oxyanions remain as distinct tetrahedra and dominate the overall structure of these ionic glasses, even with up to 30 mol% addition of NaCl. Addition of NaCl lowers the glass transition temperature (Tg) of these materials and increases the temperature between Tg and the first crystallization temperature upon heating, as determined by differential thermal analysis (DTA). The composition-dependent xPDFs indicate that chloride ions are distributed equally and increasingly around Zn, K, and Na cations as x increases.