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Geochemistry of Fluid Inclusions in Travertines From Western and Northern Turkey: Inferences on the Role of Active Faults in Fluids Circulation

2019; Wiley; Volume: 20; Issue: 11 Linguagem: Inglês

10.1029/2019gc008453

1525-2027

Andrea Luca Rizzo, İ. Tonguç Uysal, Halim Mutlu, Ezgi Ünal‐İmer, Kadir Dirik, Galip Yüce, Antonio Caracausi, Francesco Italiano, Mariagrazia Misseri, Abidin Temel, Serdar Bayarı, N. Nur Özyurt, Jian‐xin Zhao, Kıymet Deniz,

Geology and Paleoclimatology Research

Abstract The understanding of the relationship between the geochemistry of fluids circulating during travertine deposition and the presence of active faults is crucial for evaluating the seismogenetic potential of an area. Here we investigate travertines from Pamukkale and Reşadiye (Turkey), sited in seismic regions and next to thermal springs. These travertines formed ~24,500–50,000 (Pamukkale) and ~240–14,600 years (Reşadiye) BP. We characterize fluid inclusions (FIs) and studied concentration of H 2 O, CO 2 , O 2 + N 2 , and 3 He, 4 He, 20 Ne, and 40 Ar, and bulk composition (trace elements and δ 13 C‐δ 18 O). FIs from both localities are mainly primary with low salinity and homogenization temperature around 136–140 °C. H 2 O is the major component followed by CO 2 , with the highest gas content measured in Pamukkale travertines. Concentrations of Ne‐Ar together with O 2 + N 2 indicate that travertines from both areas precipitated from atmosphere‐derived fluids. The 3 He/ 4 He is 0.5–1.3 Ra in Pamukkale and 0.9–4.4 Ra in Reşadiye. Samples with R/Ra > 1 are modified by cosmogenic 3 He addition during exposure to cosmic rays. Excluding these data, FIs of Reşadiye are mostly atmosphere‐derived. This implies a shallow formation where the circulation was dominated by meteoric waters, which is consistent with their young age. Instead, FIs of Pamukkale show mixing of mantle‐, crustal‐, and atmosphere‐derived He, indicating that these travertines formed in lithospheric fractures. Based on the δ 13 C CO2 and δ 18 O of bulk rocks, we infer that travertines formed involving crustal‐ (mechanochemical rather than organic) and mantle‐derived CO 2 . Trace elements of Pamukkale and Reşadiye show comparable rare earth element patterns. We conclude that travertines formed in response of seismogenetic activity.