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BIBTEX RIS

Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

2019; Royal Society of Chemistry; Volume: 55; Issue: 94 Linguagem: Inglês

10.1039/c9cc08006f

ISSN

1364-548X

Autores

Bernardo Monteiro, Nuno A. G. Bandeira, Célia Lourenço, Ana F. Lucena, José M. Carretas, John K. Gibson, Joaquim Marçalo,

Tópico(s)

Analytical chemistry methods development

Resumo

The diverse gas-phase reactivity of [LnO 2 (NO 3 ) 2 ] − complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.

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