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Improved Interfacial Bonding Strength and Reliability of Functionalized Graphene Oxide for Cement Reinforcement Applications

2019; Wiley; Volume: 26; Issue: 29 Linguagem: Inglês

10.1002/chem.201904625

1521-3765

Nan Wang, Shuping Wang, Luping Tang, Lilei Ye, Björn Cullbrand, Abdelhafid Zehri, Behabitu Ergette Tebikachew, Johan Liu,

MXene and MAX Phase Materials

Abstract Poor bonding strength between nanomaterials and cement composites inevitably lead to the failure of reinforcement. Herein, a novel functionalization method for the fabrication of functionalized graphene oxide (FGO), which is capable of forming highly reliable covalent bonds with cement hydration products, and therefore, suitable for use as an efficient reinforcing agent for cement composites, is discussed. The bonding strength between cement and aggregates was improved more than 21 times with the reinforcement of FGO. The fabricated FGO also demonstrated many important features, including high reliability in cement pastes, good dispersibility, and efficient structural refinement of cement hydration products. With the incorporation of FGO, cement mortar samples demonstrated up to 40 % increased early and ultimate strength. Such results make the fast demolding and manufacture of light constructions become highly possible, and show strong advantages on improving productivity, saving cost, and reducing CO 2 emissions in practical applications.