Portal de Periódicos da CAPES

Kinetic Control over Self-Assembly of Semiconductor Nanoplatelets

2020; American Chemical Society; Volume: 20; Issue: 6 Linguagem: Inglês

10.1021/acs.nanolett.9b05270

1530-6992

Rebecca Momper, Heng Zhang, Shuai Chen, Henry Halim, Ewald Johannes, Stoyan Yordanov, Daniele Braga, Balthasar Blülle, David Doblas, Tobias Kraus, Mischa Bonn, Hai I. Wang, Andreas Riedinger,

Molecular Junctions and Nanostructures

Semiconductor nanoplatelets exhibit spectrally pure, directional fluorescence. To make polarized light emission accessible and the charge transport effective, nanoplatelets have to be collectively oriented in the solid state. We discovered that the collective nanoplatelets orientation in monolayers can be controlled kinetically by exploiting the solvent evaporation rate in self-assembly at liquid interfaces. Our method avoids insulating additives such as surfactants, making it ideally suited for optoelectronics. The monolayer films with controlled nanoplatelets orientation (edge-up or face-down) exhibit long-range ordering of transition dipole moments and macroscopically polarized light emission. Furthermore, we unveil that the substantial in-plane electronic coupling between nanoplatelets enables charge transport through a single nanoplatelets monolayer, with an efficiency that strongly depends on the orientation of the nanoplatelets. The ability to kinetically control the assembly of nanoplatelets into ordered monolayers with tunable optical and electronic properties paves the way for new applications in optoelectronic devices.