Two routes to platinum-based carboxylate-bridged heterometallics
2020; Elsevier BV; Volume: 508; Linguagem: Inglês
10.1016/j.ica.2020.119631
ISSN1873-3255
AutoresIlya A. Yakushev, Igor P. Stolarov, Natalia V. Cherkashina, Andrei V. Churakov, Yan V. Zubavichus, Alexander A. Markov, А. Е. Гехман, Michael N. Vargaftik,
Tópico(s)Magnetism in coordination complexes
ResumoA series of novel platinum(II) and platinum(IV) acetate-bridged heterometallic complexes was prepared by (1) one-step reaction of platinum acetate blue Pt(OOCMe)2.5–2.75 (PAB) with the complementary metal carboxylates in rather low (10–40%) yield and (2) two-step synthesis starting from potassium hexa(hydroxido)platinate(IV) in much higher (up to 90%) yield. The complexes were structurally characterized by single-crystal XRD and studied by quantum-chemical methods.
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