High resolution infrared spectra of water vapor
1969; Elsevier BV; Volume: 29; Issue: 1-3 Linguagem: Inglês
10.1016/0022-2852(69)90112-x
ISSN1096-083X
AutoresPhillip E. Fraley, K. Narahari Rao,
Tópico(s)Molecular Spectroscopy and Structure
ResumoThe ν1 and ν3 bands of H216O occurring in the region 2.5–3.0 μ were recorded with a high resolution vacuum infrared spectrograph and an analysis has been presented of the rotational structure observed. The present study led to the determination of accurate values for the ground state energy levels of the H216O molecule. The band origins obtained are: ν1 = 3657.050 cm−1 and ν3 = 3755.970 cm−1. A discussion is presented of the effects of perturbations between the upper states of the transitions involved.
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