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No Catalyst Copolymerization by Spontaneous Initiation Mechanism

1976; International Union of Pure and Applied Chemistry; Volume: 48; Issue: 3 Linguagem: Inglês

10.1351/pac197648030307

1365-3075

Takeo Sàegusa, Shiro Kobayashi, Yoshiharu Kimura,

Phosphorus compounds and reactions

A new type of copolymerization is presented here, which requires no .addedinitiator.A zwitterion I is generated by the interaction between two monomers; one monomer has nucleophilic reactivity (MN) and the other possesses electrophilic reactivity (M .. ).Two moles of the genetic zwitterion I react with each other to produce a dimeric zwitterion 2.