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Anisotropic Poisson Effect and Deformation‐Induced Fluorescence Change of Elastic 9,10‐Dibromoanthracene Single Crystals

2020; Wiley; Volume: 59; Issue: 37 Linguagem: Inglês

10.1002/anie.202006474

1521-3773

Shotaro Hayashi, Fumitaka Ishiwari, Takanori Fukushima, Shohei Mikage, Yutaka Imamura, Motomichi Tashiro, Michio Katouda,

Polydiacetylene-based materials and applications

Abstract Elastic organic crystals have attracted considerable attention as next‐generation flexible smart materials. However, the detailed information on both molecular packing change and macroscopic mechanical crystal deformations upon applied stress is still insufficient. Herein, we report that fluorescent single crystals of 9,10‐dibromoanthracene are elastically bendable and stretchable, which allows a detailed investigation of the deformation behavior. We clearly observed a Poisson effect for the crystal, where the short axes ( b and c ‐axes) of the crystal are contracted upon elongation along the long axis ( a ‐axis). Moreover, we found that the Poisson's ratios along the b ‐axis and c ‐axis are largely different. Theoretical molecular simulation suggests that the tilting motion of the anthracene may be responsible for the large deformation along the c ‐axis. Spatially resolved photoluminescence (PL) measurement of the bent elastic crystals reveals that the PL spectra at the outer (elongated), central (neutral), and inner (contracted) sides are different from each other.