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Graphene Oxide as a Mediator in Organic Synthesis: a Mechanistic Focus

2020; Wiley; Volume: 59; Issue: 47 Linguagem: Inglês

10.1002/anie.202006932

1521-3773

Lorenzo Lombardi, Marco Bandini,

Molecular Junctions and Nanostructures

Abstract Graphene oxide (GO) is experiencing growing interest by synthetic organic chemists as a promoter of chemical transformations. The synergistic role of the multiple functionalities featuring the nanostructured carbon materials and their π‐domains enables the interplay of specific activation modes towards organic compounds that can explore unprecedented chemical modifications. A detailed comprehension of the mechanistic details that govern the transformations guided by GO is a not fully solved task in the field. In this direction, more sophisticated and diversified techniques are employed, providing insights towards intriguing activation modes exerted by the π‐matrix and the oxygenated/sulfonate groups decorating the functionalized nano‐carbon material. The present Minireview accounts for a critical survey of the most recent developments in the area of GO‐mediated organic transformations with a specific focus on mechanist aspects.