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Relaxation dynamics in see-saw shaped Dy( iii ) single-molecule magnets

2020; Royal Society of Chemistry; Volume: 7; Issue: 24 Linguagem: Inglês

10.1039/d0qi01007c

ISSN

2052-1553

Autores

Katie L. M. Harriman, Jesse Murillo, Elizaveta A. Suturina, Skye Fortier, Muralee Murugesu,

Tópico(s)

Lanthanide and Transition Metal Complexes

Resumo

Unusual see-saw shaped Dy( iii ) single-molecule magnets, [K(DME) n ][L Ar Dy(X) 2 ] (L Ar = {C 6 H 4 [(2,6- i PrC 6 H 3 )NC 6 H 4 ] 2 } 2− ), X = Cl ( 1 ) and X = I ( 2 ) were synthesized and display high effective energy barriers ( U eff = 1278–1334 K) in zero field.

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