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Polycyclic Aromatic Hydrocarbons and Dust Particle Surface Interactions: Catalytic Hydrogenation of Polycyclic Aromatic Hydrocarbon Molecules under Vacuum Conditions

2020; American Chemical Society; Volume: 4; Issue: 10 Linguagem: Inglês

10.1021/acsearthspacechem.0c00145

2472-3452

G. A. Cruz-Díaz, Alessandra Ricca, A. L. Mattioda,

Quantum, superfluid, helium dynamics

This work reports experiments on the catalytic interaction occurring between polycyclic aromatic hydrocarbon (PAH) molecules and TiO2 dust grain surfaces under vacuum conditions. The investigation sheds light on the potential catalytic pathways that TiO2 dust surfaces provide in the hydrogenation of PAH molecules and the chemistry that can be driven by PAH-dust interactions under vacuum conditions. Naphthalene, anthracene, and coronene were chosen as the PAH molecules, while titanium dioxide was selected as the dust analog. PAH samples and dust analog mixtures were studied under vacuum for 24 h while monitored via diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The acquired spectra show that PAH molecules are hydrogenated when in contact with TiO2 dust particles without the need for external energy or hydrogen sources. Our results suggest that linear PAHs undergo a similar hydrogenation process where the dominant species are fully hydrogenated PAHs. For larger condensed PAHs, the hydrogenation process yields partially hydrogenated molecules. Fully hydrogenated species can be identified by a band around 2960 cm–1, while partially hydrogenated species produce a band around 2825 cm–1. In the case of the production of hydrogenated species, our results suggest that the smaller the PAH, the faster the hydrogenation rate.