Materials breaking the rules: general discussion
2021; Royal Society of Chemistry; Volume: 225; Linguagem: Inglês
10.1039/d0fd90033h
ISSN1364-5498
AutoresMatthew A. Addicoat, Thomas D. Bennett, Lee Brammer, Gavin A. Craig, Chinmoy Das, William R. Dichtel, Huan V. Doan, Austin M. Evans, Jack D. Evans, Andrew L. Goodwin, Satoshi Horike, Jianwen Jiang, Stefan Kaskel, Masako Kato, Susumu Kitagawa, Atsushi Kobayashi, Simon Krause, Christophe Lavenn, Jet‐Sing M. Lee, Anthony E. Phillips, Thomas M. Roseveare, Rochus Schmid, Mohana Shivanna, Dumitru Sirbu, Shohei Tashiro, Valeska P. Ting, Monique A. Van Der Veen, Benjamin Wilson, Pu Su Zhao,
ResumoRochus Schmid opened a discussion of the paper by Simon Krause: Very impressive presentation. As you point out, NGA is a kinetic effect, which means a barrier for squishing the MOF matrix needs to be overcome to see NGA. This implies that the guest molecules need to diffuse out of the crystal.
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