Chemometric tools to investigate complex synchrotron radiation FTIR micro-spectra: focus on historical bowed musical instruments
2021; Volume: 10; Issue: 1 Linguagem: Inglês
10.21014/acta_imeko.v10i1.836
ISSN2221-870X
AutoresGiacomo Fiocco, Silvia Grassi, Claudia Invernizzi, Tommaso Rovetta, Michela Albano, Patrizia Davit, Monica Gulmini, Chiaramaria Stani, Lisa Vaccari, Maurizio Licchelli, Marco Malagodi,
Tópico(s)Mineral Processing and Grinding
Resumo<p class="Abstract">The investigation of the coating systems used on historical bowed string musical instruments is generally highly complex due to the coatings’ reduced thickness and multi-layered structure. Furthermore, sampling is rarely feasible, and non-invasive approaches do not always allow researchers to undertake a thorough characterisation. Thus, in the rare cases of availability, the opportunity must be taken to investigate the best micro-samples in detail using a suite of analytical spectroscopic techniques that allow for obtaining various informative spectra. Their subsequent interpretation should lead to the characterisation of the finishing layers, the preparation of which involves a careful selection of organic and inorganic compounds.</p>In the present work, synchrotron radiation and micro-Fourier-transform infrared spectroscopy were combined in terms of reflection geometry and chemometrics to investigate six cross-sectioned micro-samples detached from four bowed string instruments produced by Antonio Stradivari, Francesco Ruggeri, and Lorenzo Storioni. Various chemometric tools enabled us to perform a preliminary exploration of the entire collected infrared dataset, while a classification model based on partial least squares–discriminant analysis was used to discriminate the materials through the characteristic signals. High model specificity (> 0.9) was achieved in the prediction, providing the groundwork for the application of a fast and rigorous methodological approach.
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