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BIBTEX RIS

Reactivity of [Pt(P t Bu 3 ) 2 ] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity

2021; American Chemical Society; Volume: 40; Issue: 8 Linguagem: Inglês

10.1021/acs.organomet.1c00088

ISSN

1520-6041

Autores

Nereida Hidalgo, Carlos Romero‐Pérez, Celia Maya, Israel Fernández, Jesús Campos,

Tópico(s)

Catalytic Cross-Coupling Reactions

Resumo

Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi cross-coupling reactions. Zinc-based ligands in bimetallic complexes also render unique reactivity to the transition metals at which they are bound. Here we explore the use of sterically hindered [Pt(P

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