Using silyl protecting group to enable post-deposition C–C coupling reactions of alkyne-functionalized N-heterocyclic carbene monolayers on Au surfaces
2021; Royal Society of Chemistry; Volume: 57; Issue: 43 Linguagem: Inglês
10.1039/d1cc01271a
ISSN1364-548X
AutoresIris Berg, Lillian V. A. Hale, Mazal Carmiel-Kostan, F. Dean Toste, Elad Gross,
Tópico(s)Catalytic Cross-Coupling Reactions
ResumoAlkyne-functionalized NHC ligands were protected by TIPS group that enabled surface-anchoring of NHCs with chemically-sensitive functionality and providing access, following TIPS removal, to on-surface Sonogashira cross–coupling reactions.
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