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Chiral 2D-Perovskite Nanowires for Stokes Photodetectors

2021; American Chemical Society; Volume: 143; Issue: 22 Linguagem: Inglês

10.1021/jacs.1c02675

1943-2984

Yingjie Zhao, Yuchen Qiu, Jiangang Feng, Jia‐Hui Zhao, Gaosong Chen, Hanfei Gao, Yuyan Zhao, Lei Jiang, Yuchen Wu,

Multiferroics and related materials

Structural engineering in multiple scales permits the integration of exotic properties into a single material, which boosts the development of ultracompact multifunctional devices. Layered perovskites are capable of cross-linking efficient carrier transport originating from few-layer perovskite frameworks with extended functionalities contributed by designable bulky organic cations and nanostructures, thus providing a platform for multiscale material engineering. Herein, high-performance Stokes-parameter photodetectors for arbitrary polarized light detection are realized on the basis of solution-processed chiral-perovskite nanowire arrays. The chiral ammonium cations intercalated between the perovskite layers are responsive to circularly polarized light with a maximum anisotropy factor of 0.15, while the strictly aligned nanowires with the anisotropic dielectric function result in a large polarized ratio of 1.6 to linearly polarized light. Single crystallinity and pure crystallographic orientation permit efficient in-plane carrier transport along the nanowires, yielding a responsivity of 47.1 A W–1 and a detectivity of 1.24 × 1013 Jones. By synergy of linear- and circular-polarization response with high optoelectronic performance for providing sufficient photocurrent contrasts, Stokes-parameter photodetection is demonstrated on these nanowires. Our Stokes-parameter photodetectors with a small footprint and high performances present promising applications toward polarization imaging.