Visible‐Light‐Driven Competitive Stereo‐ and Regioisomerization of ( E )‐β‐Nitroenones
2021; Wiley; Volume: 5; Issue: 9 Linguagem: Inglês
10.1002/cptc.202100081
ISSN2367-0932
AutoresCarlotta Raviola, Cristina Carrera, Massimo Serra, Alessandro Palmieri, Gabriele Lupidi, Giovanni Maestri, Stefano Protti,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoAbstract A combined experimental and computational investigation of the photoreactivity of ( E )‐β‐nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to ( E )‐β‐nitroenones and deconjugation to β‐nitro‐β,γ‐enones. Both processes are generated from the triplet excited state of the starting substrates.
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