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One-pot in situ synthesis of Cu-SAPO-34/SiC catalytic membrane with enhanced binding strength and chemical resistance for combined removal of NO and dust

2021; Elsevier BV; Volume: 420; Linguagem: Inglês

10.1016/j.cej.2021.130425

1873-3212

Jiahao Chen, Bin Wang, Kai Yuan, Yutang Kang, Shasha Feng, Feng Han, Hongmiao Wu, Rongfei Zhou, Zhaoxiang Zhong, Yiqun Fan, Weihong Xing,

Gas Sensing Nanomaterials and Sensors

• One-pot hydrothermal synthesis of high-performance Cu-SAPO-34(D)/SiC catalytic membrane. • The SiO 2 formed during the partial oxidation was ingeniously used as a Si source to participate in the growth of Cu-SAPO-34. • Enhanced binding strength and chemical resistance were both achieved for Cu-SAPO-34(D)/SiC catalytic membrane. The SiC catalytic membrane combining dust removal and denitration can realize the efficacious treatment of atmospheric pollutants. Unfortunately, a large amount of SiO 2 , formed by the partial oxidation of SiC at a high temperature, results in the decreased chemical resistance of SiC catalytic membrane. In addition, the complicated preparation processes and susceptible to loss of catalytic components under harsh conditions restrict the industrial application of SiC catalytic membranes. Here, the Cu-SAPO-34(D)/SiC catalytic membranes were directly prepared via a facile one-pot hydrothermal synthesis method, which ingeniously utilized the generated SiO 2 as a Si source to participate in the growth of Cu-SAPO-34 zeolites. Excellent binding strength and chemical resistance were simultaneously realized for the SiC catalytic membranes. As a comparison, a Cu-SAPO-34(I)/SiC catalytic membrane was fabricated via the conventional two-step ion-exchange method. The 0.2 Cu-SAPO-34(D)/SiC (Cu molar ratio of 0.2) achieved the best NH 3 -SCR performance among the prepared catalytic membranes for its highly active copper and oxygen species, abundant Lewis acid sites and remarkable redox capacity. When implementing the simultaneous removal of NO and PM, the 0.2 Cu-SAPO-34(D)/SiC catalytic membrane achieved a high NO degradation performance of 98% from 200 to 280 °C, coupled with an excellent PM 0.3 (model dust with average size of 300 nm) filtration performance of 99.99%. These results were better than those of the Cu-SAPO-34(I)/SiC catalytic membrane (92% for NO degradation and 99.98% for PM 0.3 filtration). The one-pot in situ synthesis of Cu-SAPO-34(D)/SiC catalytic membrane with enhanced binding strength and chemical resistance provides a novel strategy for preparation of high-performance SiC catalytic membrane with double benefits.