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Improving valuable metal ions capturing from spent Li-ion batteries with novel materials and approaches

2021; Elsevier BV; Volume: 338; Linguagem: Inglês

10.1016/j.molliq.2021.116703

1873-3166

Aminul Islam, Srimonta Roy, Masud Ali Khan, Pronoy Mondal, Siow Hwa Teo, Yun Hin Taufiq‐Yap, Mohammad Tofayal Ahmed, Tasrina Rabia Choudhury, G. Abdulkareem-Alsultan, Shahjalal Khandaker, Md. Rabiul Awual,

Recycling and Waste Management Techniques

• Organic acid assisted environmentally friendly efficient recovery process was reported. • The low activation energy with diffusion-controlled reaction was evident from this study. • The impact leaching chemicals on the environmental footprint was highlighted. Rapid growth in the market for batteries is imperative to meet global demand. The lack of economically feasible and environmentally benign recycling process for waste batteries may cause environmental crisis. Taking effective measures could reduce the waste-management challenge and maximize the economic benefits. In this work, environmentally benign citric acid with the presence of reluctant was used to recover cobalt, manganese, nickel and lithium from waste Lithium Nickel Manganese Cobalt oxide (NCM) batteries. Recovery of Co, Mn, Ni, and Li was optimized by varying the citric acid and H 2 O 2 concentrations, the reaction temperature and duration. The recovery of Co, Mn, Ni, and Li were 87%, 90.5%, 93.5% and 96% respectively under the optimum leaching condition of 1.2 mol/L citric acid, 10 vol% H 2 O 2 at 95° for 120 min. Interfacial reaction controlled leaching reaction at low temperature was evident from the results of leaching kinetics with apparent activation energy of 3.75, 10.405.34 and 8.72 kJ mol −1 for Co, Mn, Ni and Li, respectively. Importantly, the diffusion controlled leaching reaction was evident from the kinetic and activation energy measurement of leaching. The impact of different chemicals on the environment measured from the Biwer and Heinzle Method (BHM) revealed that the citric acid-assisted leaching process to recover valuable metals from NCM batteries was appeared lower environment impact compare to the other process reported in the literature. The high leaching efficiency and lower impact to the environment provides a novel approach for metal recovery of waste NCM batteries.