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Improved high‐resolution global and regionalized isoscapes of δ 18 O , δ 2 H and d ‐excess in precipitation

2021; Wiley; Volume: 35; Issue: 6 Linguagem: Inglês

10.1002/hyp.14254

1099-1085

Stefan Terzer‐Wassmuth, Leonard I. Wassenaar, J. M. Welker, Luis Araguás‐Araguás,

Isotope Analysis in Ecology

Abstract Patterns of δ 18 O and δ 2 H in Earth's precipitation provide essential scientific data for use in hydrological, climatological, ecological and forensic research. Insufficient global spatial data coverage promulgated the use of gridded datasets employing geostatistical techniques (isoscapes) for spatiotemporally coherent isotope predictions. Cluster‐based isoscape regionalization combines the advantages of local or regional prediction calibrations into a global framework. Here we present a revision of a Regionalized Cluster‐Based Water Isotope Prediction model (RCWIP2) incorporating new isotope data having extensive spatial coverage and a wider array of predictor variables combined with high‐resolution gridded climatic data. We introduced coupling of δ 18 O and δ 2 H (e.g., d ‐excess constrained) in the model predictions to prevent runaway isoscapes when each isotope is modelled separately and cross‐checked observed versus modelled d ‐excess values. We improved model error quantification by adopting full uncertainty propagation in all calculations. RCWIP2 improved the RMSE over previous isoscape models by ca. 0.3 ‰ for δ 18 O and 2.5 ‰ for δ 2 H with an uncertainty <1.0 ‰ for δ 18 O and < 8 ‰ for δ 2 H for most regions of the world. The determination of the relative importance of each predictor variable in each ecoclimatic zone is a new approach to identify previously unrecognized climatic drivers on mean annual precipitation δ 18 O and δ 2 H. The improved RCWIP2 isoscape grids and maps (season, monthly, annual, regional) are available for download at https://isotopehydrologynetwork.iaea.org .