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Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations

2021; Royal Society of Chemistry; Volume: 50; Issue: 36 Linguagem: Inglês

10.1039/d1dt02268g

1477-9234

Walace D. do Pim, Ingrid F. Silva, Eufrânio N. da Silva Júnior, Humberto O. Stumpf, Willian X. C. Oliveira, Emerson F. Pedroso, Carlos B. Pinheiro, Yves Journaux, Felipe Fantuzzi, Ivo Krummenacher, Holger Braunschweig, Bernd Engels, Joan Cano, Miguel Julve, Cynthia L. M. Pereira,

Lanthanide and Transition Metal Complexes

An unexpected heterobimetallic ring {CoII6CuII6} was synthesised by slow diffusion in water under ambient conditions and its dc magnetic properties were analysed through an effective Hamiltonian in the light of DFT type calculations.