Produção Nacional
Aminopropyltriethoxysilane functionalized MCM-41 and SBA-15 nanostructured materials for carbon dioxide adsorption
2021; UNIVERSIDADE FEDERAL DO RIO DE JANEIRO; Volume: 26; Issue: 4 Linguagem: Inglês
10.1590/s1517-707620210004.1385
ISSN1517-7076
AutoresMarcela Nascimento Barbosa, Maria J. F. Costa, Maricele Nascimento Barbosa, Valter J. Fernandes, Giancarlo R. Salazar‐Banda, Álvaro Reyes-Carmona, Enrique Rodríguez‐Castellón, Antônio S. Araújo,
Tópico(s)Phase Equilibria and Thermodynamics
ResumoThe design of effective CO2 capture materials is a current challenge. Here, we report the synthesis of aminosilanes-functionalized MCM-41 and SBA-15 materials with high efficiency toward carbon dioxide adsorption. The functionalization of the mesoporous silicas involves a post-synthesis method by impregnation with 3-aminopropyltriethoxysilane. The carbon dioxide adsorption capacities for the samples were carried out under ambient pressures. The results evidenced that aminosilanes with a terminal amine were functionalized through covalent coupling of this group onto the channels' surface in the ordered mesoporous silica. It means that the amine is anchored on the surface of the largest pores of the MCM-41 and SBA-15 supports. The Lagergren kinetic model evidenced the enhanced carbon dioxide adsorption capacity and stability of the functionalized ordered mesoporous molecular sieves.
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