Artigo Revisado por pares

Nondestructive Determination of Chromium, Nickel, and Zinc in Neem Leaves and Facial Care Products by Laser Induced Breakdown Spectroscopy (LIBS)

2021; Taylor & Francis; Volume: 55; Issue: 6 Linguagem: Inglês

10.1080/00032719.2021.1979572

ISSN

1532-236X

Autores

Imran Rehan, M.A. Gondal, K. Rehan, Sabiha Sultana, E.U. Khan, Mujeeb Ur Rehman, Abdul Waheed, Syed Muhammad Salman,

Tópico(s)

Heavy metals in environment

Resumo

Laser-induced breakdown spectroscopy (LIBS) was employed to determine Cr, Ni, and Zn in Neem-based beauty soaps and Neem leaves. The measurements were accomplished by attaining the optically thin plasma under the condition of local thermodynamic equilibrium (LTE) using standard calibration curve (SCC)-LIBS. The detection system was calibrated for these elements. The results showed 5.0 to 12 ppm by mass of nickel and 9.0 to 16 ppm by mass of chromium, which are above the secure allowed levels of these elements. Similarly, zinc was present from 6.2 to 14 ppm. The relative accuracy of LIBS was compared to inductively coupled plasma – optical emission spectrometry (ICP-OES) was from 0.1 to 0.3 with 2.5% error confidence.

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