Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis
2021; American Chemical Society; Volume: 122; Issue: 3 Linguagem: Inglês
10.1021/acs.chemrev.1c00614
ISSN1520-6890
AutoresChristian A. Malapit, Matthew B. Prater, Jaime R. Cabrera‐Pardo, Min Li, Tammy Dung Pham, Timothy Patrick McFadden, Skylar Blank, Shelley D. Minteer,
Tópico(s)Sulfur-Based Synthesis Techniques
ResumoSynthetic organic electrosynthesis has grown in the past few decades by achieving many valuable transformations for synthetic chemists. Although electrocatalysis has been popular for improving selectivity and efficiency in a wide variety of energy-related applications, in the last two decades, there has been much interest in electrocatalysis to develop conceptually novel transformations, selective functionalization, and sustainable reactions. This review discusses recent advances in the combination of electrochemistry and homogeneous transition-metal catalysis for organic synthesis. The enabling transformations, synthetic applications, and mechanistic studies are presented alongside advantages as well as future directions to address the challenges of metal-catalyzed electrosynthesis.
Referência(s)