Produção Nacional
Revisado por pares
Influence of halogen atoms and protonation on the photophysical properties of sulfonated porphyrins
2015; Elsevier BV; Volume: 633; Linguagem: Inglês
10.1016/j.cplett.2015.05.040
ISSN1873-4448
AutoresLeonardo De Boni, Carlos J. P. Monteiro, Cléber Renato Mendonça, Sérgio Carlos Zílio, Pablo José Gonçalves,
Tópico(s)Luminescence and Fluorescent Materials
ResumoThis work employs UV/vis absorption and Z-scan techniques to investigate how the presence of one or two halogens atoms and the macrocycle protonation affect the photophysical characteristics of sulfonated porphyrins. The results are relevant to photomedicine and photonics because they show that: (i) the insertion of halogen atoms increases the intersystem crossing quantum yield, a useful feature for photodynamic therapy, (ii) the fluorescence observed in fluorinated porphyrins shows desired characteristics for theranostics, which combine therapy and diagnostics in the same platform, and (iii) the protonation enhances the excited-state absorption in the visible region, an important feature for optical limiting.
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