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Catalytic Asymmetric Hydrogenation of δ‐Ketoesters: Highly Efficient Approach to Chiral 1,5‐Diols

2013; Wiley; Volume: 125; Issue: 30 Linguagem: Inglês

10.1002/ange.201303011

1521-3757

Xiao‐Hui Yang, Jian‐Hua Xie, Wei‐Peng Liu, Qi‐Lin Zhou,

Asymmetric Synthesis and Catalysis

Angewandte ChemieVolume 125, Issue 30 p. 7987-7990 Zuschrift Catalytic Asymmetric Hydrogenation of δ-Ketoesters: Highly Efficient Approach to Chiral 1,5-Diols† Xiao-Hui Yang, Xiao-Hui Yang State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this authorProf. Jian-Hua Xie, Corresponding Author Prof. Jian-Hua Xie jhxie@nankai.edu.cn State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this authorWei-Peng Liu, Wei-Peng Liu State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this authorProf. Qi-Lin Zhou, Corresponding Author Prof. Qi-Lin Zhou qlzhou@nankai.edu.cn State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this author Xiao-Hui Yang, Xiao-Hui Yang State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this authorProf. Jian-Hua Xie, Corresponding Author Prof. Jian-Hua Xie jhxie@nankai.edu.cn State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this authorWei-Peng Liu, Wei-Peng Liu State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this authorProf. Qi-Lin Zhou, Corresponding Author Prof. Qi-Lin Zhou qlzhou@nankai.edu.cn State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnState Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (China) http://zhou.nankai.edu.cnSearch for more papers by this author First published: 14 June 2013 https://doi.org/10.1002/ange.201303011Citations: 14 † We thank the National Natural Science Foundation of China, the National Basic Research Program of China (2010CB833300), and the "111" project of the Ministry of Education of China (Grant No. B06005) for financial support. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Inspir(o)ierend: Eine effiziente katalytische asymmetrische Hydrierung von δ-Aryl-δ-ketoestern gelang mit dem chiralen Spiroiridium-Katalysator (R)-1. Die chiralen 1,5-Diolprodukte entstanden mit exzellenter Enantioselektivität bei Umsatzzahlen (TONs) bis 100 000. TOF=Umsatzfrequenz. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description ange_201303011_sm_miscellaneous_information.pdf6.9 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume125, Issue30July 22, 2013Pages 7987-7990 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation