Artigo Revisado por pares

Introduction

2015; Elsevier BV; Volume: 44; Linguagem: Inglês

10.1016/j.lpm.2015.07.014

ISSN

2213-0276

Autores

J. C. Bousquet, R. Bourret, T. Camuzat, P. Augé, P. Domy, J. Bringer, N. Best, O. Jonquet, J.-E. de la Coussaye, M. Noguès, Jean‐Marie Robine, A. Avignon, H. Blain, Bernard Combe, Gérard Dray, Vincent Dufour, M. Fouletier, N. Giraudeau, D. Hève, Catherine Jeandel, I. Laffont, Dominique Larrey, D. Laune, C. Laurent, P. Marès, Chantal Marion, E. Pastor, J.-Y. Pélissier, F. Radier-Pontal, J. Reynes, E. Royère, Marc Ychou, A. Bedbrook, S. Granier, F. Abecassis, S. Albert, P.-A. Adnet, B. Alomène, M. Amouyal, S. Arnavielhe, Trias Asteriou, V. Attalin, P. Aubas, C. Azevedo, M. Badin, Bakhti, G. Baptista, Benoît G. Bardy, M.-P. Battesti, O. Bénézet, Pierre Louis Bernard, Claudine Berr, J. Berthe, Xavier Bobia, Joël Bockaert, C. Boegner, Sylvie Boichot, H.-Y. Bonnin, P Boulet, S. Bouly, C. Boubakri, Arnaud Bourdin, J.‐L. Bourrain, G. Bourrel, Vincent Bouix, Cyril Breuker, V. Bruguière, J. Burille, S. Cade, Davide Caimmi, M.-V. Calmels, William Camu, G. Canovas, V. Carre, Giacomo Cavalli, Guillaume Cayla, R. Chiron, P.-G. Claret, P. Coignard, F. Coroian, David Costa, Pierre Alves Costa, Cottalorda, B. Coulet, A. -L. Coupet, Marie-Christine Courrouy-Michel, Philippe Courtet, Jean‐Paul Cristol, V. Cros, Frédéric Cuisinier, C. Daïen, Marianna Danko, P. Dauenhauer, M. Dauzat, M. David, J.–M. Davy, Didier Delignières, P. Démoly, J. Desplan, H. Dhivert‐Donnadieu, Pierre Dujols, Arnaud Dupeyron, G Dupeyron, Agnès Oude Engberink, M. Enjalbert, Charles Fattal, J. Fernandes, Pierre Fesler, P. Fraisse, Jérôme Froger, P. Gabrion, E. Galano, M. Gellerat-Rogier, A. Gellis, A.-Y. Goucham, Farès Gouzi, F. Gressard, Jean‐Christophe Gris, B. Guillot, David Guiraud, V. Handweiler, H. Hantkié, Maurice Hayot, C. Hérisson, C. Héroum, D. Hoa, S. Jacquemin, S. Jaber, D. Jakovenko, C. Jorgensen, L. Journot, Michel Kaczorek, P. Kouyoudjian, Pierre Labauge, L. Landreau, M. Lapierre, C. Leblond, Marie-Suzanne Léglise, Jean-Marc Lemaı̂tre, V. Le Moing, A. Le Quellec, F. Leclercq, Sylvain Lehmann, Béatrice Lognos, J.-M. Lussert, Alain Makinson, Kévin Mandrick, V. Marmelat, P. Martin-Gousset, A. Matheron, G. Mathieu, Marc Meissonnier, Grégoire Mercier, Patrick Messner, Cyril Meunier, Michel Mondain, Raúl Juntas Morales, Jacques Morel, David Morquin, Denis Mottet, Philippe Nérin, P. Nicolas, Grégory Ninot, F. Nouvel, J.-P. Ortiz, D. Paccard, Guillaume Pandraud, M.-P. Pasdelou, Jean Luc Pasquié, K. Patte, Stéphane Perrey, Yves‐Marie Pers, Marie‐Christine Picot, Jean‐Philippe Pin, N. Pinto, E. Porte, F. Portejoie, Jean Louis Pujol, Xavier Quantin, I. Quéré, N. Raffort, Sofiane Ramdani, Jean Ribstein, I. Rédini-Martinez, Sylvain Richard, Karen Ritchie, Jean-Pierre Riso, François Rivier, C. Rolland, F. Roubille, Denis Sablot, J.-L. Savy, L. Schifano, Pierre Sénesse, R. Sicard, B. Soua, Yannick Stéphan, D. Strubel, Ariane Sultan, Taddei-Ologeanu, G. Tallon, Michel Tanfin, Hervé Tassery, Isabel Tavares, K. Torre, J. Touchon, Vincent Tribout, Alain Uziel, Philippe Van de Perre, X. Vasquez, Jean‐Michel Verdier, Céline Vergne-Richard, Grégoire Vergotte, Laurence Vian, Christine Viarouge-Reunier, François Vialla, F. Viart, Max Villain, Maxime Villiet, E. Viollet, Anne Wojtusciszyn, M. Aoustin, Céline Bourquin, J. Mercier,

Resumo

This study presents the use of oedometric compression test in order to evaluate the breakdown of a protective layer acting as a diffusion barrier ("barrier effect") occurring during cone calorimeter tests for ethylene-vinyl acetate copolymer/aluminium trihydroxide (EVA/ATH) composites. The formation of an alumina layer at the sample surface during burning insulates thermally the underlying material and reduces the heat release rate. The efficiency of this barrier depends on the cohesion of the layer formed. This cohesion depends on the ability of the particles (ATH and synergistic mineral fillers) to self-arrange. During the test, the breakdown of this barrier can lead to an increase in HRR.The oedometric compression test allows assessing the ability of fillers to form a cohesive layer. Results obtained from compression modulus of filler powders are directly related to some aspects of the heat release rate curve of composites measured in cone calorimeter tests. Indeed, the appearance and the intensity of the second pHRR (related to the breakdown of the barrier layer) in cone calorimeter test are related to the slope of oedometric compression curve.

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