Portal de Periódicos da CAPES

Synthesis, Structure, and Greatly Improved Reversible O 2 Binding in a Structurally Modulated μ‐η 2 :η 2 ‐Peroxodicopper( II ) Complex with Room‐Temperature Stability

2003; Wiley; Volume: 116; Issue: 3 Linguagem: Inglês

10.1002/ange.200352737

1521-3757

Masahito Kodera, Yuuji Kajita, Y. Tachi, Kou Katayama, Koji Kano, Shun Hirota, Shuhei Fujinami, Masatatsu Suzuki,

Metal complexes synthesis and properties

Angewandte ChemieVolume 116, Issue 3 p. 338-341 Zuschrift Synthesis, Structure, and Greatly Improved Reversible O2 Binding in a Structurally Modulated μ-η2:η2-Peroxodicopper(II) Complex with Room-Temperature Stability† Masahito Kodera Prof. Dr., Masahito Kodera Prof. Dr. mkodera@mail.doshisha.ac.jp Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorYuuji Kajita, Yuuji Kajita Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorYoshimitsu Tachi Dr., Yoshimitsu Tachi Dr. Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorKou Katayama, Kou Katayama Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorKoji Kano Prof. Dr., Koji Kano Prof. Dr. Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorShun Hirota Dr., Shun Hirota Dr. Kyoto Pharmaceutical University, Nakauchi-cho, Misasagi, Yamashina-ku, Kyoto 607-8414, JapanSearch for more papers by this authorShuhei Fujinami Dr., Shuhei Fujinami Dr. Department of Chemistry, Kanazawa University, Kakuma-machi, Kanazawa 920–1192, JapanSearch for more papers by this authorMasatatsu Suzuki Prof. Dr., Masatatsu Suzuki Prof. Dr. Department of Chemistry, Kanazawa University, Kakuma-machi, Kanazawa 920–1192, JapanSearch for more papers by this author Masahito Kodera Prof. Dr., Masahito Kodera Prof. Dr. mkodera@mail.doshisha.ac.jp Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorYuuji Kajita, Yuuji Kajita Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorYoshimitsu Tachi Dr., Yoshimitsu Tachi Dr. Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorKou Katayama, Kou Katayama Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorKoji Kano Prof. Dr., Koji Kano Prof. Dr. Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan, Fax: (+81) 774-65-6848Search for more papers by this authorShun Hirota Dr., Shun Hirota Dr. Kyoto Pharmaceutical University, Nakauchi-cho, Misasagi, Yamashina-ku, Kyoto 607-8414, JapanSearch for more papers by this authorShuhei Fujinami Dr., Shuhei Fujinami Dr. Department of Chemistry, Kanazawa University, Kakuma-machi, Kanazawa 920–1192, JapanSearch for more papers by this authorMasatatsu Suzuki Prof. Dr., Masatatsu Suzuki Prof. Dr. Department of Chemistry, Kanazawa University, Kakuma-machi, Kanazawa 920–1192, JapanSearch for more papers by this author First published: 29 December 2003 https://doi.org/10.1002/ange.200352737Citations: 12 † This work was supported by the Grant-in-Aid for Scientific Research (A) (14340210) from JSPS and the Aid of Doshisha University's Research Promotion Fund. We thank Prof. Dr. Teizo Kitagawa, Institute for Molecular Science, for permission to use the resonance Raman equipment. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Die einfache O2-Freisetzung aus einem Oxyhämocyanin-Modellkomplex gelang erstmals mit dem neuen, bei Raumtemperatur stabilen μ-η2:η2-Peroxodikupferkomplex 1. Die Verlängerung der Cu-O-Bindungen, die durch die Brückenkopf-Methylgruppen des Liganden hervorgerufen wird, ist die Ursache für die einfache O2-Freisetzung. Die Bindung von CO und O2 durch 1 ist UV/Vis-spektroskopischen Untersuchungen zufolge vollständig reversibel (siehe Bild). Citing Literature Volume116, Issue3January 5, 2004Pages 338-341 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation