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Montmorillonite‐Entrapped Sub‐nanoordered Pd Clusters as a Heterogeneous Catalyst for Allylic Substitution Reactions

2007; Wiley; Volume: 119; Issue: 18 Linguagem: Alemão

10.1002/ange.200604644

1521-3757

Takato Mitsudome, Kenta Nose, Kohsuke Mori, Tomoo Mizugaki, Kohki Ebitani, Koichiro Jitsukawa, Kiyotomi Kaneda,

Catalytic Cross-Coupling Reactions

Angewandte ChemieVolume 119, Issue 18 p. 3352-3354 Zuschrift Montmorillonite-Entrapped Sub-nanoordered Pd Clusters as a Heterogeneous Catalyst for Allylic Substitution Reactions† Takato Mitsudome Dr., Takato Mitsudome Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKenta Nose, Kenta Nose Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohsuke Mori Dr., Kohsuke Mori Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorTomoo Mizugaki Dr., Tomoo Mizugaki Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohki Ebitani Dr., Kohki Ebitani Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKoichiro Jitsukawa Prof. Dr., Koichiro Jitsukawa Prof. Dr. Department of Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, JapanSearch for more papers by this authorKiyotomi Kaneda Prof. Dr., Kiyotomi Kaneda Prof. Dr. kaneda@cheng.es.osaka-u.ac.jp Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this author Takato Mitsudome Dr., Takato Mitsudome Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKenta Nose, Kenta Nose Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohsuke Mori Dr., Kohsuke Mori Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorTomoo Mizugaki Dr., Tomoo Mizugaki Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKohki Ebitani Dr., Kohki Ebitani Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this authorKoichiro Jitsukawa Prof. Dr., Koichiro Jitsukawa Prof. Dr. Department of Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, JapanSearch for more papers by this authorKiyotomi Kaneda Prof. Dr., Kiyotomi Kaneda Prof. Dr. kaneda@cheng.es.osaka-u.ac.jp Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260Search for more papers by this author First published: 23 April 2007 https://doi.org/10.1002/ange.200604644Citations: 24 † This investigation was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. We thank the center of excellence (21COE; program “Creation of Integrated Ecochemistry”, Osaka University) and Dr. Uruga (Spring-8) for XAFS measurements. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Gefangen aktiv: Stabile Pd-Cluster zwischen den Schichten von Montmorillonit katalysieren allylische Substitutionen effizient, wobei die koordinativ ungesättigten Pd-Atome die Bildung von π-Allylpalladium-Zwischenstufen ermöglichen (siehe Schema). Der Heterogenkatalysator lässt sich ohne Verlust an Aktivität oder Selektivität wiederverwenden. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z604644_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume119, Issue18April 27, 2007Pages 3352-3354 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation