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BIBTEX RIS

Hexaethylguanidinium Salts

2014; Multidisciplinary Digital Publishing Institute; Volume: 4; Issue: 3 Linguagem: Inglês

10.3390/cryst4030404

ISSN

2073-4352

Autores

Robert Salchner, Volker Kahlenberg, Thomas Gelbrich, Klaus Wurst, Martin Rauch, Gerhard Laus, Herwig Schottenberger,

Tópico(s)

Polyoxometalates: Synthesis and Applications

Resumo

Crystal structures of five hexaethylguanidinium salts (PF6− 1, FeCl4− 2, CuCl42−·H2O 3, CoBr42−/Br−·H2O 4, bistriflimide 5) were determined. Short interionic contacts were identified. Cyclic voltammetry of 2 revealed an electrochemical window from +1.0 to −1.5 V with a single Fe(III)/Fe(II) redox event at −0.27 V on a gold electrode versus Ag/AgCl.

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