Synthesis of acyloin natural products by Mukaiyama hydration
2022; Royal Society of Chemistry; Volume: 20; Issue: 19 Linguagem: Inglês
10.1039/d2ob00651k
ISSN1477-0539
AutoresMichael Ricca, Wei Zhang, J.-H. Li, Thomas Fellowes, Jonathan M. White, Paul S. Donnelly, Mark A. Rizzacasa,
Tópico(s)Marine Sponges and Natural Products
ResumoThe preparation of Co( ii ) and Co( iii ) SALPN type catalysts for the Mukaiyama hydration of enones, and their application to the synthesis of acyloin natural products is described. An acyloin rearrangement was key to the success of this approach.
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