Direct Observation of Cyclic Carbenium Ions and Their Role in the Catalytic Cycle of the Methanol‐to‐Olefin Reaction over Chabazite Zeolites
2013; Wiley; Volume: 125; Issue: 44 Linguagem: Inglês
10.1002/ange.201303586
ISSN1521-3757
AutoresShutao Xu, Anmin Zheng, Yingxu Wei, Jingrun Chen, Jinzhe Li, Yueying Chu, Mozhi Zhang, Quanyi Wang, You Zhou, Jinbang Wang, Feng Deng, Zhongmin Liu,
Tópico(s)Metal-Organic Frameworks: Synthesis and Applications
ResumoCarbeniumionen in Zeolithen: Mit 13C-NMR-Spektroskopie wurden erstmals zwei wichtige Carbeniumionen unter Bedingungen der Methanol-zu-Olefin(MTO)-Reaktion über Chabazit-Zeolithen beobachtet. Die entscheidenden Rollen dieser Ionen im MTO-Zyklus wurden mithilfe kombinierter experimenteller und theoretischer Studien aufgezeigt. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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