Synthesis, Crystal Structure, Spectroscopic and Magnetic Properties of an Unprecedented Three-Dimensional CuII Coordination Compound of 1,2-Bis(1,2,4-triazol-4-yl)ethane
2000; Wiley; Volume: 2000; Issue: 2 Linguagem: Inglês
10.1002/(sici)1099-0682(200002)2000
ISSN1099-0682
AutoresYann Garcia, Petra J. van Koningsbruggen, H. Kooijman, Anthony L. Spek, Jaap G. Haasnoot, Olivier Kahn,
Tópico(s)Metal complexes synthesis and properties
ResumoEuropean Journal of Inorganic ChemistryVolume 2000, Issue 2 p. 307-314 Full Paper Synthesis, Crystal Structure, Spectroscopic and Magnetic Properties of an Unprecedented Three-Dimensional CuII Coordination Compound of 1,2-Bis(1,2,4-triazol-4-yl)ethane Yann Garcia, Yann GarciaSearch for more papers by this authorPetra J. van Koningsbruggen, Petra J. van KoningsbruggenSearch for more papers by this authorHuub Kooijman, Huub Kooijman Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, NL-3584 CH Utrecht, The NetherlandsSearch for more papers by this authorAnthony L. Spek, Anthony L. Spek Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, NL-3584 CH Utrecht, The NetherlandsSearch for more papers by this authorJaap G. Haasnoot, Jaap G. Haasnoot Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, NL-2300 RA Leiden, The NetherlandsSearch for more papers by this authorOlivier Kahn†, Olivier Kahn† Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, F-33608 Pessac, FranceSearch for more papers by this author Yann Garcia, Yann GarciaSearch for more papers by this authorPetra J. van Koningsbruggen, Petra J. van KoningsbruggenSearch for more papers by this authorHuub Kooijman, Huub Kooijman Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, NL-3584 CH Utrecht, The NetherlandsSearch for more papers by this authorAnthony L. Spek, Anthony L. Spek Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, NL-3584 CH Utrecht, The NetherlandsSearch for more papers by this authorJaap G. Haasnoot, Jaap G. Haasnoot Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, NL-2300 RA Leiden, The NetherlandsSearch for more papers by this authorOlivier Kahn†, Olivier Kahn† Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS No 9048, F-33608 Pessac, FranceSearch for more papers by this author First published: 26 January 2000 https://doi.org/10.1002/(SICI)1099-0682(200002)2000:2 3.0.CO;2-MCitations: 47AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract A novel three-dimensional copper(II) compound of the formula [Cu3(btre)5(H2O)2](ClO4)6·H2O (btre = 1,2-bis(1,2,4-triazol-4-yl)ethane) has been synthesized. The structure has been solved at 150 K by single-crystal X-ray analysis. The compound [C30H44Cu3N30O2·6(ClO4)·H2O] crystallizes in the triclinic space group P1bar with a = 12.488(1), b = 13.195(1), c = 19.756(2) Å, α = 78.959(8), β = 84.553(8), γ = 63.869(7)°, V = 2868.4(5) Å3, Z = 2 (trinuclear CuII units), 6484 reflections [I > 4σ(I)], RF = 0.0581, wR2 = 0.1214. The structure of this coordination polymer consists of a three-dimensional network built up from linear trinuclear CuII cations of formula [Cu3(btre)5(H2O)2]6+. This crystallographically independent unit comprises a linear array of three CuII ions linked by triple N1,N2-1,2,4-triazole bridges, yielding Cu1–Cu2 = 3.893(1) Å and Cu2–Cu3 = 3.889(1) Å. These linear trinuclear CuII units are linked by various pathways involving tridentate and tetradentate bridging btre ligands, which yields an unprecedented three-dimensional network. The CuII ions are weakly antiferromagnetically coupled with J = –1.01(2) cm–1 (based on the Hamiltonian: H = –J[SCu1·SCu2 + SCu2·SCu3] using the expression for the molar magnetic susceptibility S = 1/2 of a linear trinuclear system). The nature and the magnitude of the antiferromagnetic exchange have been discussed on the basis of the structural features. References 1 R. Prins, P. J. M. W. L. Birker, J. G. Haasnoot, G. C. Verschoor, J. Reedijk, Inorg. Chem. 1985, 24, 4128. 10.1021/ic00218a031 CASWeb of Science®Google Scholar 2 A. Bencini, D. Gatteschi, C. Zanchini, J. G. Haasnoot, R. Prins, J. Reedijk, Inorg. Chem. 1985, 24, 2812. 10.1021/ic00212a022 CASWeb of Science®Google Scholar 3 W. M. E. Koomen-van Oudenniel, R. A. G. de Graaff, J. G. Haasnoot, R. Prins, J. Reedijk, Inorg. Chem. 1989, 28, 1128. 10.1021/ic00305a024 CASWeb of Science®Google Scholar 4 P. J. van Koningsbruggen, J. G. Haasnoot, R. A. G. de Graaff, J. Reedijk, S. Slingerland, Acta Crystallogr. 1992, C48, 1923. CASGoogle Scholar 5 P. M. Slangen, P. J. van Koningsbruggen, K. Goubitz, J. G. Haasnoot, J. Reedijk, Inorg. Chem. 1994, 33, 1121. 10.1021/ic00084a025 CASWeb of Science®Google Scholar 6 P. M. Slangen, P. J. van Koningsbruggen, J. G. Haasnoot, J. Jansen, S. Gorter, J. Reedijk, H. Kooijman, W. J. J. Smeets, A. L. Spek, Inorg. Chim. Acta 1993, 212, 289. 10.1016/S0020-1693(00)92336-3 CASWeb of Science®Google Scholar 7 P. J. van Koningsbruggen, J. G. Haasnoot, H. Kooijman, J. Reedijk, A. L. Spek, Inorg. Chem. 1997, 36, 2487. 10.1021/ic9611002 CASPubMedWeb of Science®Google Scholar 8 Y. Garcia, P. J. van Koningsbruggen, G. Bravic, P. Guionneau, D. Chasseau, G. V. Cascarano, J. Moscovici, K. Lambert, A. Michalowicz, O. Kahn, Inorg. Chem. 1997, 36, 6357. 10.1021/ic970895p CASWeb of Science®Google Scholar 9 P. J. van Koningsbruggen, M. W. Gluth, V. Ksenofontov, D. Walcher, D. Schollmeyer, G. Levchenko, P. Gütlich, Inorg. Chim. Acta 1998, 273, 54. 10.1016/S0020-1693(97)05914-8 CASWeb of Science®Google Scholar 10 P. J. van Koningsbruggen, J. G. Haasnoot, H. Kooijman, J. Reedijk, A. L. Spek, J. Chem. Soc., Dalton Trans., submitted. Google Scholar 11[11a] O. Kahn, Molecular Magnetism, VCH Publishers, New York, 1993. Google Scholar– [11b] O. Kahn, C. Jay-Martinez, Science 1998, 79, 44. 10.1126/science.279.5347.44 CASWeb of Science®Google Scholar 12 O. Kahn, E. Codjovi, Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade, L. Sommier, in Molecule-Based Magnetic Materials (Eds.: M. M. Turnbull, T. Sugimoto, L. K. Thompson), ACS Symposium Series No. 644, American Chemical Society, Washington DC, 1996, p. 298. 10.1021/bk-1996-0644.ch020 Web of Science®Google Scholar 13 O. Kahn, J. Kröber, C. Jay, Adv. Mater. 1992, 4, 718. 10.1002/adma.19920041103 CASWeb of Science®Google Scholar 14 C. Jay, F. Grolière, O. Kahn, J. Kröber, Mol. Cryst. Liq. Cryst. 1993, 234, 255. 10.1080/10587259308042924 CASWeb of Science®Google Scholar 15 J. Kröber, J.-P. Audière, R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolière, C. Jay, A. Bousseksou, J. Linarès, F. Varret, A. Gonthier-Vassal, Chem. Mater. 1994, 6, 1404. 10.1021/cm00044a044 CASWeb of Science®Google Scholar 16 J. Kröber, E. Codjovi, O. Kahn, F. Grolière, C. Jay, J. Am. Chem. Soc. 1993, 115, 9810. 10.1021/ja00074a062 CASWeb of Science®Google Scholar 17 L. G. Lavrenova, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva, S. V. Larionov, Koord. Khim. 1986, 12, 207; CASGoogle Scholar Chem. Abstr. 1986, 104, 218034b. Google Scholar 18 L. G. Lavrenova, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva, S. V. Larionov, J. Struct. Chem. 1993, 34, 960. 10.1007/BF00752874 Web of Science®Google Scholar 19 L. G. Lavrenova, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva, S. V. Larionov, Koord. Khim. 1990, 16, 654; CASWeb of Science®Google Scholar Chem. Abstr. 1991, 114, 34747m. Google Scholar 20 L. G. Lavrenova, N. G. Yudina, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva, S. V. Larionov, Polyhedron 1995, 14, 1333. 10.1016/0277-5387(94)00398-X CASWeb of Science®Google Scholar 21 J. G. Haasnoot, in Magnetism: A Supramolecular Functio (Ed: O. Kahn), Kluwer Academic Publishers, Dordrecht, The Netherlands, 1996, p. 299. 10.1007/978-94-015-8707-5_16 Web of Science®Google Scholar 22 Y. Garcia, P. J. van Koningsbruggen, E. Codjovi, R. Lapouyade, O. Kahn, L. Rabardel, J. Mater. Chem. 1997, 7, 857. 10.1039/a701242j CASWeb of Science®Google Scholar 23 N. V. Bausk, S. B. Érenburg, L. N. Mazalov, L. G. Lavrenova, V. N. Ikorskii, J. Struct. Chem. 1994, 35, 509. 10.1007/BF02578362 Web of Science®Google Scholar 24 N. V. Bausk, S. B. Érenburg, L. G. Lavrenova, L. N. Mazalov, J. Struct. Chem. 1995, 36, 925. 10.1007/BF02578550 Web of Science®Google Scholar 25 S. B. Érenburg, N. V. Bausk, N. A. Varnek, L. G. Lavrenova, J. Magn. Magn. Mater. 1996, 157/158, 595. 10.1016/0304-8853(95)00969-8 CASWeb of Science®Google Scholar 26 S. B. Érenburg, N. V. Bausk, L. G. Lavrenova, V. A. Varnek, L. N. Mazalov, Solid State Ionics 1997, 101–103, 571. 10.1016/S0167-2738(97)84085-4 Web of Science®Google Scholar 27 E. Codjovi, L. Sommier, O. Kahn, C. Jay, New. J. Chem. 1996, 20, 503. CASWeb of Science®Google Scholar 28 R. Bronisz, K. Drabent, P. Polomka, M. F. Rudolf, Conference Proceedings, ICAME95 1996, 50, 11. CASWeb of Science®Google Scholar 29 P. J. van Koningsbruggen, Y. Garcia, E. Codjovi, R. Lapouyade, L. Fournès, O. Kahn, L. Rabardel, J. Mater. Chem. 1997, 7, 2069. 10.1039/a702690k CASWeb of Science®Google Scholar 30[30a] G. Vos, R. A. Le Fěbre, R. A. G. de Graaff, J. G. Haasnoot, J. Reedijk, J. Am. Chem. Soc. 1983, 105, 1682. 10.1021/ja00344a060 CASWeb of Science®Google Scholar– [30b] G. Vos, R. A. G. de Graaff, J. G. Haasnoot, A. M. van der Kraan, P. de Vaal, J. Reedijk, Inorg. Chem. 1984, 23, 2905. 10.1021/ic00186a038 CASWeb of Science®Google Scholar 31 J. J. A. Kolnaar, G. van Dijk, H. Kooijman, A. L. Spek, V. Ksenofontov, P. Gütlich, J. G. Haasnoot, J. Reedijk, Inorg. Chem. 1997, 36, 2433. 10.1021/ic9612010 CASPubMedWeb of Science®Google Scholar 32 Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade, L. Rabardel, O. Kahn, M. Wierczorek, R. Bronisz, Z. Ciunik, M. F. Rudolf, C. R. Acad. Sci. Paris 1998, IIc, 523. Google Scholar 33 Y. Garcia, P. J. van Koningsbruggen, R. Lapouyade, L. Fournès, L. Rabardel, O. Kahn, V. Ksenofonov, G. Levchenko, P. Gütlich, Chem. Mater. 1998, 10, 2426. 10.1021/cm980107+ CASWeb of Science®Google Scholar 34 V. P. Sinditskii, V. I. Sokol, A. E. Fogel'zang, M. D. Dutov, V. V. Serushkin, V. M. A. Porai-Koshits, B. S. Svetlov, Russ. J. Inorg. Chem. 1987, 32, 1149. Google Scholar 35 G. Vos, A. J. de Kok, G. C. Verschoor, Z. Naturforsch. 1981, 36b, 809. CASGoogle Scholar 36 M. Thomann, O. Kahn, J. Guilhem, F. Varret, Inorg. Chem. 1994, 33, 6029. 10.1021/ic00104a010 CASWeb of Science®Google Scholar 37 M. Biagini–Cingi, A. M. Manotti-Lanfredi, F. Ugozzoli, J. G. Haasnoot, J. Reedijk, Gazz. Chim. Ital. 1994, 124, 509. CASGoogle Scholar 38 W. Vreugdenhil, S. Gorter, J. G. Haasnoot, J. Reedijk, Polyhedron 1985, 4, 1769. 10.1016/S0277-5387(00)84174-1 CASWeb of Science®Google Scholar 39 W. Vreugdenhil, J. H. van Diemen, R. A. G. de Graaff, J. G. Haasnoot, J. Reedijk, A. M. van der Kraan, O. Kahn, J. Zarembowitch, Polyhedron 1990, 24, 2971. 10.1016/S0277-5387(00)84209-6 CASWeb of Science®Google Scholar 40 A. Ozarowski, Y. Shunzhong, B. R. McGarvey, A. Mislankar, J. E. Drake, Inorg. Chem. 1991, 30, 3167. 10.1021/ic00016a013 CASWeb of Science®Google Scholar 41 W. Vreugdenhil, J. G. Haasnoot, R. A. G. de Graaff, H. A. Nieuwenhuis, D. Reefman, J. Reedijk, Acta Crystallogr. 1987, C43, 1527. CASGoogle Scholar 42 W. Vreugdenhil, Ph. D. Thesis, Leiden University, 1987. Google Scholar 43 P. Domiano, Cryst. Struct. Commun. 1977, 6, 503. CASGoogle Scholar 44 W. Vreugdenhil, J. G. Haasnoot, J. Reedijk, J. S. Wood, Inorg. Chim. Acta 1990, 167, 109. 10.1016/S0020-1693(00)83943-2 CASWeb of Science®Google Scholar 45 B. J. Hathaway, D. E. Billing, Coord. Chem. Rev. 1972, 5, 143. 10.1016/S0010-8545(00)80135-6 CASWeb of Science®Google Scholar 46 K. Nakamoto, in Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed., Wiley, New York, 1997. Google Scholar 47 D. B. Brown, J. R. Wasson, J. W. Hall, W. E. Hatfield, Inorg. Chem. 1977, 16, 2526. 10.1021/ic50176a021 CASWeb of Science®Google Scholar 48 L. Antolini, A. C. Fabretti, D. Gatteschi, A. Giusti, R. Sessoli, Inorg. Chem. 1991, 30, 4858. 10.1021/ic00025a034 CASWeb of Science®Google Scholar 49 L. P. Wu, Y. Yamagiwa, T. Kuroda-Sowa, T. Kamikawa, M. Munakata, Inorg. Chim. Acta 1997, 256, 155. 10.1016/S0020-1693(96)05424-2 CASWeb of Science®Google Scholar 50 P. J. van Koningsbruggen, J. G. Haasnoot, W. Vreugdenhil, J. Reedijk, O. Kahn, Inorg. Chim. Acta 1995, 239, 5. 10.1016/0020-1693(95)04680-1 CASWeb of Science®Google Scholar 51 H. O. Bayer, R. S. Cook, W. C. von Meyer, U.S. Patent 3, 821, 376, 28/6/ 1974. Google Scholar 52 J. L. de Boer, A. J. M. Duisenberg, Acta Crystallogr. 1984, A40, C410. Google Scholar 53 A. L. Spek, J. Appl. Crystallogr. 1988, 21, 578. 10.1107/S002188988800490X Web of Science®Google Scholar 54 G. M. Sheldrick, SHELXS86, Program for crystal structure determination, University of Göttingen, Germany, 1986. Google Scholar 55 G. M. Sheldrick, SHELXL-97, Program for crystal structure refinement, University of Göttingen, Germany, 1997; Google Scholar International Tables for Crystallography (Ed.: A. J. C. Wilson), vol. C, Kluwer, Academic Publishers, Dordrecht, The Netherlands, 1992. Google Scholar 56 A. L. Spek, Acta Crystallogr. 1990, A46, C34. Google Scholar Citing Literature Volume2000, Issue2February 2000Pages 307-314 ReferencesRelatedInformation
Referência(s)