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Platinum‐Catalyzed Intramolecular [4C+3C] Cycloaddition between Dienes and Allenes

2007; Wiley; Volume: 120; Issue: 5 Linguagem: Inglês

10.1002/ange.200704566

1521-3757

Beatriz Trillo, Fernando López, Moisés Gulı́as, Luís Castedo, José L. Mascareñas,

Synthetic Organic Chemistry Methods

Angewandte ChemieVolume 120, Issue 5 p. 965-968 Zuschrift Platinum-Catalyzed Intramolecular [4C+3C] Cycloaddition between Dienes and Allenes† Beatriz Trillo, Beatriz Trillo Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorFernando López Dr., Fernando López Dr. qojoselm@usc.es Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorMoisés Gulías Dr., Moisés Gulías Dr. Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorLuis Castedo Prof. Dr., Luis Castedo Prof. Dr. Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorJosé L. Mascareñas Prof. Dr., José L. Mascareñas Prof. Dr. Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this author Beatriz Trillo, Beatriz Trillo Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorFernando López Dr., Fernando López Dr. qojoselm@usc.es Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorMoisés Gulías Dr., Moisés Gulías Dr. Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorLuis Castedo Prof. Dr., Luis Castedo Prof. Dr. Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this authorJosé L. Mascareñas Prof. Dr., José L. Mascareñas Prof. Dr. Departamento de Química Orgánica, Universidad de Santiago de Compostela, Facultad de Química, 15782, Santiago de Compostela, Spain, Fax: (+34) 981-595-012 http://qoweb.usc.es/jlmgroup/index.htmlSearch for more papers by this author First published: 11 January 2008 https://doi.org/10.1002/ange.200704566Citations: 43 † This work was supported by the Spanish MEC (SAF2007-61015), Consolider Ingenio 2010 (CSD2007-00006), and the Xunta de Galicia (GRC2006/132). B.T. and M.G. thank the Spanish M.E.C. and Xunta de Galicia for predoctoral fellowships. F.L. thanks the Xunta de Galicia (PGIDIT06PXIB209126PR) for research support and the Spanish MEC for a Ramon y Cajal contract. Lucía Saya is gratefully acknowledged for technical support. We also thank Johnson–Matthey for the generous gift of metal complexes. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Systeme mit Siebenringen: Die drei Kohlenstoffatome von Allenylfragmenten können mit Dienen durch eine platinkatalysierte intramolekulare [4C+3C]-Cycloaddition zu siebengliedrigen Carbocyclen kombiniert werden (siehe Schema). Die Umwandlung überführt leicht zugängliche acyclische Vorstufen direkt und atomökonomisch in Polycyclen mit Cycloheptanringen. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2008/z704566_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume120, Issue5January 18, 2008Pages 965-968 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation