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Thiatriphyrin(2.1.1): A Core‐Modified Contracted Porphyrin

2013; Wiley; Volume: 125; Issue: 12 Linguagem: Inglês

10.1002/ange.201209678

ISSN

1521-3757

Autores

Daiki Kuzuhara, Yuka Sakakibara, Shigeki Mori, Tetsuo Okujima, Hidemitsu Uno, Hiroko Yamada,

Tópico(s)

Magnetism in coordination complexes

Resumo

Angewandte ChemieVolume 125, Issue 12 p. 3444-3447 Zuschrift Thiatriphyrin(2.1.1): A Core-Modified Contracted Porphyrin† Dr. Daiki Kuzuhara, Dr. Daiki Kuzuhara Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan)Search for more papers by this authorYuka Sakakibara, Yuka Sakakibara Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan)Search for more papers by this authorDr. Shigeki Mori, Dr. Shigeki Mori Department of Molecular Science, Integrated Center for Sciences, Ehime University, Matsuyama 790-8577 (Japan)Search for more papers by this authorProf. Dr. Tetsuo Okujima, Prof. Dr. Tetsuo Okujima Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577 (Japan)Search for more papers by this authorProf. Dr. Hidemitsu Uno, Prof. Dr. Hidemitsu Uno Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577 (Japan)Search for more papers by this authorProf. Dr. Hiroko Yamada, Corresponding Author Prof. Dr. Hiroko Yamada [email protected] Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan) CREST, JST, Chiyoda-ku, Tokyo 102-0075 (Japan)Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan)Search for more papers by this author Dr. Daiki Kuzuhara, Dr. Daiki Kuzuhara Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan)Search for more papers by this authorYuka Sakakibara, Yuka Sakakibara Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan)Search for more papers by this authorDr. Shigeki Mori, Dr. Shigeki Mori Department of Molecular Science, Integrated Center for Sciences, Ehime University, Matsuyama 790-8577 (Japan)Search for more papers by this authorProf. Dr. Tetsuo Okujima, Prof. Dr. Tetsuo Okujima Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577 (Japan)Search for more papers by this authorProf. Dr. Hidemitsu Uno, Prof. Dr. Hidemitsu Uno Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577 (Japan)Search for more papers by this authorProf. Dr. Hiroko Yamada, Corresponding Author Prof. Dr. Hiroko Yamada [email protected] Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan) CREST, JST, Chiyoda-ku, Tokyo 102-0075 (Japan)Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192 (Japan)Search for more papers by this author First published: 11 February 2013 https://doi.org/10.1002/ange.201209678Citations: 18 † We thank S. Katao for the measurements of X-ray diffraction and M. Yamamura and Y. Nishikawa for ESIMS measurements. This research was partly supported by Grants-in-Aid (No. 24655034 to H.Y. and D.K.) and the Green Photonics Project at NAIST sponsored by the Ministry of Education, Culture, Sports, Science and Technology, MEXT (Japan). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Das kontrahierte Porphyrin Thiatriphyrin(2.1.1) mit modifiziertem Kern, das als freie Base instabil ist, wurde durch McMurry-Kupplung mit p-Tolylsubstituenten ausgestattet und dann in verschiedene Alkoxy-substituierte Derivate umgewandelt (siehe Schema; DBU=1,8-Diazabicyclo[5.4.0]undec-7-en). Diese wurden in Gegenwart von Trifluoressigsäure in protonierte Thiatriphyrine(2.1.1) überführt, die moderate Aromatizität aufweisen. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. 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