Synthesis and Reactions of the Pestalotiopsin Skeleton
2008; Wiley; Volume: 120; Issue: 30 Linguagem: Inglês
10.1002/ange.200801900
ISSN1521-3757
AutoresThomas Baker, David J. Edmonds, Deborah Hamilton, Christopher J. O’Brien, David J. Procter,
Tópico(s)Microbial Natural Products and Biosynthesis
ResumoFamilienbande: Das Strukturgerüst der Pestalotiopsine wurde durch SmI2-vermittelte Cyclisierung und Nozaki-Hiyama-Kishi-Kupplung zum Aufbau der vier- bzw. neungliedrigen Ringe erzeugt. Eine stereoselektive säurevermittelte Cyclisierung des Pestalotiopsin-Gerüsts öffnete einen präparativen Zugang zur bisher unerforschten Familie der Taedolidol-Naturstoffe. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2008/z801900_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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