A Three‐Coordinate Copper(II) Amide from Reductive Cleavage of a Nitrosamine
2009; Wiley; Volume: 122; Issue: 5 Linguagem: Inglês
10.1002/ange.200905171
ISSN1521-3757
AutoresM.M. Melzer, Susanne Mossin, Xuliang Dai, A.M. Bartell, Pooja Kapoor, Karsten Meyer, Timothy H. Warren,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoAngewandte ChemieVolume 122, Issue 5 p. 916-919 Zuschrift A Three-Coordinate Copper(II) Amide from Reductive Cleavage of a Nitrosamine† Marie M. Melzer Dr., Marie M. Melzer Dr. Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorSusanne Mossin Dr., Susanne Mossin Dr. Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen (Germany) Current address: Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of DenmarkSearch for more papers by this authorXuliang Dai Dr., Xuliang Dai Dr. Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorAshley M. Bartell, Ashley M. Bartell Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorPooja Kapoor, Pooja Kapoor Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorKarsten Meyer Prof. Dr., Karsten Meyer Prof. Dr. Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen (Germany)Search for more papers by this authorTimothy H. Warren Prof., Timothy H. Warren Prof. [email protected] Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this author Marie M. Melzer Dr., Marie M. Melzer Dr. Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorSusanne Mossin Dr., Susanne Mossin Dr. Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen (Germany) Current address: Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of DenmarkSearch for more papers by this authorXuliang Dai Dr., Xuliang Dai Dr. Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorAshley M. Bartell, Ashley M. Bartell Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorPooja Kapoor, Pooja Kapoor Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this authorKarsten Meyer Prof. Dr., Karsten Meyer Prof. Dr. Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen (Germany)Search for more papers by this authorTimothy H. Warren Prof., Timothy H. Warren Prof. [email protected] Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227 (USA), Fax: (+1) 202-687-6209Search for more papers by this author First published: 20 January 2010 https://doi.org/10.1002/ange.200905171Citations: 14 † The authors acknowledge funding from the National Science Foundation (CHE-0135057 and CHE-0716304 to T.H.W.), the Deutsche Forschungsgemeinschaft (SFB 583), and the Alexander von Humboldt Foundation (re-invitation award to T.H.W.). M.M.M. thanks the Luce Foundation for a pre-doctoral fellowship. We are grateful to Prof. Tom Cundari of the University of North Texas for helpful suggestions. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Ein NO-vum: Ein Kupfer(I)-β-diketiminat aktiviert das Nitrosamin Ph2NNO unter Bildung eines seltenen, dreifach koordinierten Kupfer(II)-amids, 1. Die Reaktion dieses Amids mit NO-Gas setzt Ph2NNO wieder frei und liefert eine gemischtvalente Spezies mit NO-funktionalisierten β-Diketiminatliganden (2; Cu hellblau, N dunkelblau, O rot). Somit können an einem gewöhnlichen Kupferzentrum Spaltung und Bildung der R2N-NO-Bindung gleichermaßen stattfinden. 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